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Even when not required by environmental regulations, the following
best practices are recommended.
Activity: Chemical Storage
- Store incompatible chemicals separately, i.e., separate acid,
bases, organic solvents and oxidisers.
- Flammable chemicals should be stored in a ventilated flammables
storage cabinet.
- Do not store chemicals in corridors or doorways or other means
of egress.
- Chemical containers should be stored in pans, or trays made
of compatible material that will act as secondary containment
if a container breaks or leaks.
- Do not store open containers of chemicals in laboratory hoods.
- Minimise the storage of chemicals on laboratory bench tops.
- Store the minimum quantity of chemicals necessary.
- Store acids and bases below eye level.
- Make sure container lids are secure.
- Make sure containers are properly labelled. Labels should include
name of the chemical, hazards and precautions required. Do not
reuse containers without relabelling the exterior and defacing
the old label.
- Keep a chemical spill kit available adequate to clean up the
largest anticipated spill that could occur in the lab. Train personnel
on spill clean up procedures.
- Clean up all spills quickly.
- Maintain general housekeeping in the lab. Keep bench tops, aisles,
and walkways clear.
- Have an emergency evacuation plan. Train personnel in key elements
of the plan and run periodic drills.
- Minimise the storage of combustible material in labs.
- Perform and document in a logbook periodic inspections of chemical
storage areas for leaks, container deterioration. Inspection items
should include the following: external corrosion, structural failure,
spills and overfills due to operator error, failure of piping
system (pipes, pumps, flanges, couplings, hoses, and valves),
visual inspections of new tanks or containers for loose fittings,
poor welds, and improper or poorly fitted gaskets, and inspect
tank foundations and storage area coatings for integrity.
- Accept chemical donations only after careful consideration of
how the chemical will be used and after ascertaining that the
chemical is not contaminated, out of date, etc.
Container Management
- Ensure containers with incompatible wastes are not stored near
each other so that if the containers were to break there would
not be an adverse reaction.
- Clearly label waste containers with the words "Hazardous
Waste" and name of the waste type and hazards (e.g., "corrosive,
toxic").
- Log chemicals and quantities added to waste containers as chemicals
are added.
- Train laboratory personnel on safe procedures for transferring
chemicals to waste containers.
- Maintain separate containers for broken glassware, sharps, hazardous
and radioactive waste.
- Maintain separate waste containers for compatible waste streams
(acids, bases, oxidizers, organic solvents, radioactive waste)
- Do not store waste containers where they have the potential
to freeze or are exposed to high heat.
- Keep waste containers in tubs or other secondary containment.
- Waste containers should be in good condition, not rusted or
dented.
- Make sure waste containers are compatible with the waste type
they are expected to contain.
- Keep an adequate spill control kit nearby and know how to use
it.
- Clean up spills quickly if you are properly trained and equipped
to do so.
- Periodically inspect the waste container area and log observations
and corrective actions taken.
- When handling waste containers use mechanical aids such as drum
lifts, drum hand trucks, drum dollies etc. Do not roll drums on
their side or edge.
Activity: Emergency Equipment
Even when not required by environmental regulations, the following
best practices for laboratory emergency equipment are recommended.
- Emergency eyewash stations & showers in areas where there
is the potential to come into contact with hazardous chemicals,
with unobstructed access from any point in the lab within 10 seconds,
and located on the same level as the potential hazard.
- Fire extinguishers easily accessible, and of of size and type
to be effective against an anticipated fire.
- Fire Blankets.
- Communications systems including telephones, radios, alarms.
- Emergency personal protective equipment including SCBA's, disposable
coveralls, gloves, eye protection, short-term escape respirators.
- Spill control equipment including, spill pillows, absorbent
pads, drum berms, drain plugs, hand pumps, neutralisation solutions.
- Air monitoring instrumentation, either portable or fixed systems
if needed.
- First aid kit, including burn kit.
- Periodic inspection of equipment to ensure its effectiveness
and availability.
- Hands-on training for laboratory personnel on the use of emergency
equipment.
Activity: Sinks and Drains
Even when not required by environmental regulations, the following
best practices are recommended.
- Train laboratory personnel in waste management practices. Be
sure they know what can and cannot be disposed of down the drain.
- Periodic inspections should be performed to ensure proper disposal
procedures are being performed.
- Substitute the use of biodegradable cleaners for chromic-sulfuric
acid when washing laboratory glassware.
- Use microchemistry techniques where possible.
- Plan experiments to minimise waste generation.
- Clean up any spill promptly.
- Keep rags, mops, absorbents, and other cleanup supplies readily
accessible to all work areas.
- Keep a spill control kit and drain plugs nearby.
- Check with the local POTW or onsite wastewater treatment plant
regarding what can be safely disposed of down sinks and drains.
- Close off or guard laboratory hood cup sinks from spill within
the hood.
Activity: Laboratory Hoods
Even when not required by environmental regulations, the following
best practices are recommended to minimize the emission of hazardous
air pollutants from laboratory hoods.
- Identify opportunities to eliminate or reduce emissions.
- Use microchemistry techniques.
- Do not store chemicals in laboratory hoods.
- Make sure containers that hold volatile chemicals are securely
capped.
- Maintain pollution control equipment and keep maintenance records.
- Maintain laboratory ventilation systems and keep maintenance
records.
Activity: Gas Cylinder Management
Laboratory personnel may occasionally be required to handle compressed
gas cylinders. Employees that perform work involving compressed gas
cylinders should be familiar with their hazards and safe practices.
Even when not required by environmental or H & S regulations,
the following best practices are recommended.
Identification and Labelling
- All gas cylinders must be clearly labelled.
- Do not accept a compressed gas cylinder for use that does not
legibly identify its contents by name.
- Never rely on the color of the cylinder for identification.
- Gas lines leading from a compressed gas supply must be labelled
to identify the gas, the laboratory or area served, and the relevant
emergency telephone numbers.
- Signs must be posted in areas where flammable compressed gases
are stored, identifying the substances and appropriate precautions
(e.g., HYDROGEN - FLAMMABLE GAS - NO SMOKING - NO OPEN FLAMES).
Engineering Controls / Design Considerations
- Keep hazardous gas cylinders in gas cylinder cabinets or racks,
with the exception of cylinders containing a non-toxic, flammable
gas, and cylinders used in fume hood applications.
- Place a smoke detector adjacent to flammable gas cylinders,
connected if possible to the building alarm system. If possible,
interlock smoke detector activation with the shutdown of hazardous
gas flow.
- Connect all ducts used to exhaust hazardous compressed gas cylinders
or gas-carrying components to a ventilation alarm.
- Place a safety shower or eyewash with a wand in areas where
corrosive gases are used or stored.
- Make sure that all gas piping is compatible with the gases used
and capable of withstanding full cylinder pressure.
- Never lubricate, modify, force, or tamper with a cylinder valve.
Use the appropriate regulator on each gas cylinder.
- Use check valves when there is the possibility of back flow
into the cylinder.
Using Cylinders
- Always use safety glasses with side shields when handling and
using compressed gases, especially when connecting and disconnecting
compressed gas regulators and lines.
- Never use a cylinder that cannot be identified positively.
- Never use a cylinder of compressed gas without a pressure-reducing
regulator attached to the cylinder valve.
Activity: Mixed Waste
Even when not required by environmental regulations, the following
best practices are recommended for minimising and managing mixed
wastes.
- Replace toluene based liquid scintillation fluid with non-ignitable
fluid. This replacement results in having a potential mixed waste
into a radioactive waste.
- Use low volume liquid scintillation vials.
- Use radionuclides with short half lives that can be allowed
to decay in storage prior to disposal.
- Avoid cross contamination of other waste streams.
Activity: Toxic Use & Waste Minimisation
Toxic use reduction and waste minimisation activities apply
not only to wastes but includes the management of releases to air,
water, and generation of solid and non-hazardous waste. Best practices
for a number of environmental areas related to pollution prevention
in laboratories are described below.
Air Quality
- Implement microscale chemistry techniques where possible.
- Make sure the caps and container lids on volatile chemicals
are secure.
- Do not store chemicals in laboratory fume hoods.
- Substitute less toxic or less volatile chemicals in processes
where possible.
Wastewater
- Review processes and procedures for opportunities to minimise
wastewater generation.
- Implement microscale chemistry techniques where possible.
- Use organic dishwashing solutions instead of chromic-sulfuric
acid mixtures when washing glassware if possible.
Hazardous Waste
- Minimise the amount of chemicals stored in the lab to the minimum
quantities needed to avoid having to dispose of chemicals that
expire or deteriorate during storage.
- Develop an inventory of chemicals no longer needed in your lab
that could possibly be used by another.
- Where possible substitute less toxic chemicals where toxic chemicals
are used in a procedure or process.
- Evaluate ways to reduce the amount of toxic chemicals used in
lab procedures.
- Re-use or recycle spent solvent.
- Avoid contaminating non-hazardous waste streams with hazardous,
radioactive or biohazardous material.
- If possible, small amounts of hazardous waste may be effectively
treated in the laboratory, rendering it non-hazardous prior to
disposal. On site treatment techniques may include:
- pH neutralization
- Treatment in accumulation containers, i.e., precipitation
of heavy metals,
- Onsite recycling
- Burning in boilers or furnaces
- Include detoxification or waste treatment steps in lab procedures
Radioactive and Mixed Waste
- Replace toluene based liquid scintillation fluid with non-ignitable
fluid making a potential mixed waste into a radioactive waste.
- Use low volume liquid scintillation vials.
Non-Hazardous Waste
- Use two sided copying
- Make procedures, MSDSs, manuals, etc. available electronically
- Use e-mail instead of hard copies
- Share trade periodicals rather than maintaining multiple subcriptions
- Use reusable containers
- Use rechargeable batteries
Activity: Training
More detailed training information is provided in the regulatory
requirements sections of the EVC. Even when not required by environmental
regulations, the following best practices are recommended.
- Training courses should be developed in a systematic manner,
including the development of a course lesson plan. Course development
should include:
- An assessment of training needs
- Learning objectives
- Structured course design and presentation
- Development of evaluation methods
- Methods to determine successful completion of the course
- The physical training environment should be:
- Safe
- Comfortable
- Free from distractions
- Trainers should have adequate technical knowledge to teach
the course content, and be familiar with training delivery methods
and adult learning.
- Trainees should have the opportunity to ask questions about
material presented.
- Training for physical activities and skills such as use of
personal protective equipment (PPE) or container handling should
include a hands-on skills development and assessment segment.
- Trainees should be evaluated to assess their level of understanding,
skill development and abilities.
- Trainers should be evaluated to assess subject matter knowledge,
and presentation skills to assist in course improvement.
- Training records/documentation should be readily retrievable
and include:
- Date, location and duration of the course
- Title and description of course content
- Names of instructors
- Names of attendees
- If training certificates are issued to attendees they should
include the following:
- Name of the student
- Title of the course
- Date and duration of class
- Statement of successful completion
- Reference to regulatory citation if training is intended to
meet specific regulatory requirement.
- Name, signature and date of instructor
Activity: Waste Determinations
Even when not required by regulations, the following best
practices are recommended.
- Retain records of analytical data that is used in making waste
determinations for a minimum of three years, keep these files
in an organised manner so they are easy to find.
- Develop a filing system for waste determination files, sorted
by waste stream.
- Ensure that waste determination is confirmed by the generator,
even if an outside company performs the analysis and renders an
opinion of the waste determination.
- Avoid mixing waste in the same container, which can result in
a waste classification for the entire volume of waste that is
not necessary.
- Review your waste determination process every six months at
a minimum to evaluate whether these determinations are accurate
and consistent.
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